IJSEA Archive (Special Issue - NCRTAM )
International Journal of Science and Engineering Applications (IJSEA) (Special Issue - NCRTAM )
Growth and Characterisation of a New Semi–Organic Nonlinear Optical TTMZS Single Crystal
Keywords:Crystal growth; Crystal Structure; X-ray Diffraction; Semi-Organic Material; Nonlinear Material.
A new semi-organic nonlinear optical crystal called Tris Thiourea Magnesium Zinc sulphate (TTMZS) was
synthesized. TTMZS single crystals were grown from an aqueous solution using the Slow Evaporation
method. The solubility of TTMZS was determined for various temperatures. Single Crystal X-ray
Diffraction (XRD) study was carried-out to identify the lattice parameters. Various diffracting planes
of the grown crystal were identified from the powder XRD study. Fourier Transform Infrared (FT-IR)
studies confirm the various functional groups present in the grown crystal. The transmission spectrum
of this crystal shows that the lower cut off wavelength lies at 280 nm. The thermal analysis confirmed
that the crystal is stable up to 248.46°C. The Nonlinear Optical (NLO) property of the grown crystal
has been confirmed by Kurtz powder Second Harmonic Generation (SHG) test.
[1] Monaco, S.B., Devis L.E., Velsk, S.P., Wang, F.T. Eimeral, D., J. Cryst. Growth 85 (1987) 252.
[2] Marcy,H.O., Rosker, M.J. Warren, L.F., Cunningham, P.H. Thomas,, C.A., Deloach, L.A.,
Velsko, S.P., Ebbers, C.A., Liao, J.H., Kanatzidis, M.G., Opt.Lett. 20 (1995) 252.
[3] Jiang, M.H., Fang, Q., Adv. Mater. 119 (1999) 1147.
[4] Coe, B.J., Mccleverty,J.A., Meyer, T.J. (Eds.), Comprehensive Coordination Chemistry
II, vol. 9, Elsevier Pergamon, Oxford, UK, 2004, pp. 621–687.
[5] Marcy, H.O., Warren, L.F., Webb, M.S., Ebbers, C.A. Velsko, S.P., Kennedy, G.C.,
Catella, G.C., Appl. Opt. 31 (1992) 5051.
[6] Venkataraman, V., Subramaniam, C.K., Bhat, H.L J. Appl. Phys. 77 (1995)6049.
[7] Ramajothi, J. Dhanuskodi, S. Nagarajan, K. Cryst. Res. Technol. 39 (2004)414.
[8] Ramabadran, U.B., Zelmon, D.E., Kennedy, G.C., Appl. Phys. Lett. 60 (1992)2589.
[9] Ramabadron, U.B., Mcpherson, A.L. Zelmon, D.E. J. Appl. Phys. 76 (1994) 1150.
[10] Venkataramanan, V., Dhanaraj, G., Wadhawan, V.K. Sherwood, J.N., Bhat, H.L. J. Cryst.
Growth 154 (1995) 92.
[11] Ushasree, P.M., Jayavel, R., Subramanian Ramaswamy, P., J. Cryst.Growt 197 (1999) 216.
[12] Ghatak, A., Thyagarajan, K. Optical Electronics, Cambridge University Press, ,1994
@article{bhuvaneswarincrtam011017,
title = "Growth and Characterisation of a New Semi–Organic Nonlinear Optical TTMZS Single Crystal ",
journal = "International Journal of Science and Engineering Applications (IJSEA)",
volume = "NCRTAM",
number = "1",
pages = "75 - 78",
year = "2013",
author = " Bhuvaneswari Arvind, R.Dhanasekaran ",
}