IJSEA Archive (Special Issue - NCRTAM )
International Journal of Science and Engineering Applications (IJSEA) (Special Issue - NCRTAM )
Effect of Hippuric Acid on the Growth, Structural and Optical Properties of Non Linear Optical Crystals
A Kumaresh, R. Arun Kumar, G. Sankar, P. Selvakumar, M. Arivanandhan, Y. Hayakawa, H. Kawai
Keywords:solution growth, single crystals, Powder XRD, UV-Vis-NIR, FTIR, Powder SHG test, optical property.
Non-linear optical potassium dihydrogen phosphate (KDP) and ammonium dihydrogen phosphate (ADP) single crystals with 1 mol% of hippuric acid dopant were grown from aqueous solution by employing slow evaporation technique. With appropriate dopants, the KDP and ADP crystals exhibit several desirable properties. Crystallinity of the grown crystals was studied by powder XRD analysis. The bonding structure and molecular associations were analyzed by FTIR spectroscopy. It also confirms the functional groups present in the grown crystals. UV-Vis-NIR spectral analysis was carried out to study the optical characteristics of the crystals which reveal that the cutoff wavelength for both hippuric acid doped KDP and ADP crystals is around 300 nm. Second harmonic generation (SHG) test adopting the Kurtz Perry technique revealed that the SHG efficiency has increased due to doping when compared with pure KDP and ADP crystals.
Shirsat .M.D., Hussaini .S.S, Dhumane .N.R, and
Dongre V.G. (2008).Crist.Res.Technol.43:756-761.
[2] Kannan .V., Bairava Ganesh R, Sathyalakshmi R.,
Rajesh N.P and Ramasamy .P, (2002). Mat. Lett. 56:
578.
[3] Chenthamarai .S,.Jayaraman D, Meera . Subramanian.
C and Ramasamy .P, Mat. Chem. Phys. 64, 179
(2000).
[4] Chenthamarai S.,.Jayaraman D, Meera K.,
Santharagavan P., Subramanian C. Bocelli G.
and.Ramasamy .P, Cryst.Engg.4,37 (2001).
[5] Rai R.N.,.Ramasamy P, and.Lan C.W. J.Cryst. Growth
235, 499 (2002).
[6] Vijayan N., Ramesh Babu R. Gunasekaran .M,
Gopalakrishnan R., Kumaresan R .Ramasamy P and
Lan C.W., J.Cryst.Growth 249, 309 (2003).
[7] Selvakumar S., Ravikumar S.M., Rajarajan K., Joseph
A., Arul Pragasa, Rajasekaran S.A., Thamizharasan K.,
and Sagayaraj P. , J. Cryst.Growth 11, 2607 (2006).
[8] Angelimery P.A. and Dhanuskodi S., Cryst. Res.
Technol. 36, 1231 (2001).
[9] Dhanuskodi S. and Vasantha K., Cryst. Res. Technol.
39, (2004). 259
[10] Ariponnammal S., Radhika S., Selva and R.
VictorJeya N., Cryst. Res. Technol 40,786 (2005).
[11] HajaHameed A.S., Ravi G., Dhanasekaran R. and
Ramasamy P. J. Cryst. Growth 212, 217 (2000).
[12] LakshmanaPerumal C.K., Archakkarvarthi A. and
Santharagavan P. J. Cryst. Growth. 241, 200 (2002).
[13] Chemla D.S., Zyss J. (Eds), Nonlinear Optical
Properties of Organic Molecules and Crystals, vol.1,
Orlando, Academic Press, 1987, pp. 23-187.
[14] Krishna Mohan M., Jagannathan K., Ponnusamy S.
and Muthamizhchelvan C., J. Phys. Chem. Solids.72
(2011) 1273-1278.
[15] Dhanaraj P.V., Rajesh N.P., Ramasamy P.,
Jayaprakasan, Mahadevan C.K., and
Bhagavannarayana G., “Enhancement of stability of
growth, structural and NLO properties of KDP
crystals due to additive along with seed rotation,”
Crystal Research and Technology, vol.44, no.1,pp. 54-
60,2009.
@article{kumareshnncrtam011022,
title = "Effect of Hippuric Acid on the Growth, Structural and Optical Properties of Non Linear Optical Crystals ",
journal = "International Journal of Science and Engineering Applications (IJSEA)",
volume = "NCRTAM",
number = "1",
pages = "93 - 96",
year = "2013",
author = " A Kumaresh, R. Arun Kumar, G. Sankar, P. Selvakumar, M. Arivanandhan, Y. Hayakawa, H. Kawai ",
}