Authors can submit their research articles to editor@ijsea.com  

Processing Charges

IJSEA is index with

 

 

 

 

 

 

 

IJSEA Archive (Volume 4, Issue 6)

International Journal of Science and Engineering Applications (IJSEA)  (Volume 4, Issue 6 November-December 2015)

Corrosion Behaviour of 6061 Al-SiC Composites in KOH Medium

Arun V K,Arun T A

10.7753/IJSEA0406.1007




 PDF 



Keywords: Corrosion, 6061 Al-SiC composite, KOH, 8-Hydroxyquinoline, Tafel.

Abstract References BibText


        The present research work deals with the corrosion behaviour of 6061 Al-15% (vol) SiC(P) composites. The addition of the reinforcement like SiC to Aluminium has been reported to decrease the corrosion resistance of the matrix due to several reasons, one of them being galvanic action between the reinforcement and the matrix. In the present work, the corrosion behaviour of 6061 Al-15% (vol) SiC(P) composites in KOH at different concentration (0.5M, 1M, 1.5M) and different temperature (300C, 350C, 400C, 450C, 500C) was determined by Tafel extrapolation technique. The inhibition action of 8-Hydroxyquinoline on corrosion behaviour of 6061 Al-15% (vol) SiC(P) composites in KOH at different concentration of inhibitor (200ppm, 400ppm); different concentration of medium (0.5M, 1M,1.5M) and different temperature (300C, 350C, 400C, 450C, 500C) was investigated. The results indicate that corrosion rate of Al-SiC composite in KOH increases as the concentration of medium increases and also as temperature of medium increases. The results indicate that the inhibitor is moderately effective in inhibiting the corrosion of 6061 Al-15% (vol) SiC(P) composites. As the inhibitor concentration increases, the corrosion rate decreases. The surface morphology of the metal surface was investigated using scanning electron microscope (SEM). Activation energy was evaluated using Arrhenius equation, and enthalpy of activation and entropy of activation values were calculated using transition state equation.


[1] Aprael, S. Y. and Huda, A. D.,”Corrosion Inhibition of Aluminum Alloy 5083”. Iraqi Joumal of Chemical and Petroleum Engineering,Vol.10 No.4 (December 2009) 19-25.
[2] ASM Handbook.(2005).Volume13B, Corrosion: Materials, ASM International, Ohio.
[3] Bhat, M. S. N., Surappa, M. K. and Nayak, H. V. S. (1991).“Corrosion Behaviour of Silicon Carbide particle reinforced 6061/Al alloy composites.” J. Mater. Sci., 26, 4991-4996.
[4] Bockris, J. O. M. and Swinkels, D. A. J. (1964).“Adsorption of n-Decylamine on solid metal electrodes.”J. Electrochem. Soc., 111(8), 736-743.
[5] Candan, S. and Bilgic, E. (2004). “Corrosion behavior of Al-60 vol. % SICp composites in NaCl solution.”Mater.Lett., 58, 2787-2790.
[6] Chawla, K. K. (1998). Composite Materials- Science and engineering, Springer, Newyork.
[7] Davis, J. R. (1993). Aluminium and Aluminium Alloys. ASM International, Ohio.
[8] Fischer, H. (1972). “The Inhibition of Vapor-phase Corrosion.”Werkst.Korros, 23, 445-465.
[9] Fontanna, M. G. (2005). Corrosion Engineering,3rd Edition,McGraw Hill, USA.
[10] Ghali, E. (2010). Corrosion Resistance of Aluminium and Meganesium Alloys Understanding, Performance and Testing, John Wiley & Sons, Inc., Publication, New Jersey.
[11]Hausler, R. H. (1983). Paper 19, International Conference on Corrosion Inhibition. National Association of Corrosion Engineers, Dallas, paper 19.
[12]Hollingsworth, E. H. and Hunsicker, H. Y. (1987). Metals Hand Book, Vol.13, 9th Edition, 583-609, ASM International, Metals Park, Ohio.
[13]Lamakaa, S. V., Zheludkevich, M. L., Yasakau, K. A., Montemorb, M. F. and Ferreira, M. G. S., “High effective organic corrosion inhibitors for 2024 Aluminium alloy.”ElectrochimicaActa52 (2007) 7231–7247.
[14]Lloyd, D. J. (1994). “Particle Reinforced Aluminium and Magnesium Matrix Composites.” International Metals Review. 39(1), 1-3.
[15]Lorenz, K., Zellner, B. and Ber.Bunsenges.(1984). “Laser Photolysis/resonance fluorescence study of the rate constants for the reactions of Hydroxyl radicals with ethane and propene.”Phys. Chem., 88, 1128-1231.
[16]Lorenz, W. J and Mansfield, F. (1983).Paper 2, International Conference on Corrosion Inhibition. National Association of Corrosion Engineers, Dallas.
[17]Nayak, J. and Hebbar, K. R. (2008).Trans. Indian. Inst. Met., 61, 221-224.
[18]Paciej, R. C. and Agarwala, V. S. (1986).“ Metallurgical Variables Influencing the Corrosion Susceptibility of a Powder Metallurgy SiCw/ Al Composite.” Corrosion, 42, 718-728.
[19]Philip, A. S. (2007). Corrosion of Linings and Coatings- Cathodic and Inhibitor Protection and Corrosion Monitoring, Taylor and Francis group, USA.
[20]Reena, K. P. D., Nayak, J. and Shetty, N. A., “Corrosion behavior of 6061/Al-15 vol. pct. SiC(p) compositeand the base alloy in sodium hydroxide solution.” Arabian Journal of Chemistry (2012).
[21]Roberge, P.R. (2000). Handbook of Corrosion Engineering, McGraw, USA.
[22]Sun, H., Koo, E. Y. and Wheat, H. G. (1991).“ Corrosion behaviour of SiCp/6061 Al Metal Matrix Composites.” Corrosion, 47, 741-753.
[23]Trzaskoma, P. P., McCafferty, E. and Crowe, C. R. (1983). “Corrosion behaviour of SiC/Al Metal Matrix Composites.”Electrochem Soc. J, 130, 1804-1809.
[24]Uhling, H. H. and Revie, R. W. (2008).Corrosion and corrosion control, John Wiley & Sons, Inc., Publication, New Jersey.
[25]Winkler, S. L., Ryan, M .P. and Flower, H. M. (2004). “Pitting corrosion in cast 7XXX Aluminium alloys and fibre reinforced MMCs.” Corrosion Science., 46, 893-902.
[26]Winston, R. R (2011).Uhligs Corrosion Hand Book,John Wiley & Sons, Inc., Publication, New jersey.
[27]Zaki, A. (2006). Principles of Corrosion Engineering and Corrosion Control,Elseveir, UK.


@article{Arun04061007,
title = " Corrosion Behaviour of 6061 Al-SiC Composites in KOH Medium ",
journal = "International Journal of Science and Engineering Applications (IJSEA)",
volume = "4",
number = "6",
pages = "366 - 375",
year = "2015",
author = " Arun V K,Arun T A ",
}